UV Curing of Epoxy Resins
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Epoxy monomer + Photoinitiator → Cross-linked polymer
Descripción general
Cationic photoinitiators generate strong acids upon UV exposure, which catalyze the ring-opening polymerization of epoxy groups. Unlike free-radical photopolymerization, cationic UV curing continues after the light is removed (dark cure) and is not inhibited by oxygen. This produces highly cross-linked, chemically resistant networks.
Ejemplo cotidiano
UV-curable epoxy adhesives are used in electronics assembly, bonding glass to metal, and sealing fiber optic connectors.
Importancia industrial
Tecnología clave en recubrimientos industriales, adhesivos de alta resistencia, encapsulados electrónicos y odontología.
Propiedades
- Tipo
- Photochemical
- Reversible
- No
- Energía
- Exotérmico
- ΔH
- -95,0 kJ/mol
- Catalizador
- Cationic photoinitiator