Aluminum Chloride and Chloride Ion (Lewis Acid-Base)
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AlCl3 + Cl− → AlCl4−
Descripción general
Aluminum chloride acts as a Lewis acid, accepting a lone pair from chloride ion to form the tetrachloroaluminate anion. AlCl₃ has an electron-deficient aluminum center that readily accepts electron pairs. This Lewis acidity makes AlCl₃ one of the most important catalysts in organic chemistry.
Participantes
Ejemplo cotidiano
Friedel-Crafts reactions used to produce polystyrene and other important materials rely on AlCl₃ acting as a Lewis acid catalyst.
Importancia industrial
El cloruro de aluminio se utiliza como catalizador en la alquilación y acilación de Friedel-Crafts, en el craqueo del petróleo y en la producción de alquilatos detergentes.
Propiedades
- Tipo
- Acid-Base
- Reversible
- Sí
- Energía
- Exotérmico
- ΔH
- -55,0 kJ/mol