Electrowinning of Zinc
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ZnSO4 + H2O → Zn + H2SO4 + ½O2
Descripción general
Zinc electrowinning (electroextraction) deposits zinc metal from purified zinc sulfate solution onto aluminum cathodes. The cathode deposit is stripped every 24–48 hours and melted into zinc ingots. The regenerated sulfuric acid is recycled to leach more zinc ore. About 90% of the world's zinc is produced by this hydrometallurgical route.
Participantes
| Rol | Sustancia | Coeficiente | Estado |
|---|---|---|---|
| Reactivo | Water H₂O | 1 | (l) |
| Producto | Zinc Zn | 1 | (s) |
| Producto | Sulfuric Acid H₂SO₄ | 1 | (aq) |
Ejemplo cotidiano
Zinc used in galvanized steel, brass, and zinc alloy die-castings is predominantly produced by this electrowinning process.
Importancia industrial
La electroextracción produce aproximadamente 12 millones de toneladas de zinc al año. También se aplica al cobre, cobalto, níquel y manganeso en procesos hidrometalúrgicos.
Propiedades
- Tipo
- Electrochemical
- Reversible
- No
- Energía
- Endotérmico
- ΔH
- 469,0 kJ/mol