Hydrogen Sulfide Oxidation by Chlorine
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H2S + Cl2 → 2HCl + S
Descripción general
Chlorine oxidizes hydrogen sulfide to elemental sulfur while being reduced to hydrochloric acid. Sulfur is oxidized from -2 to 0. This reaction is used in removing hydrogen sulfide from natural gas (sweetening) and in treating hydrogen sulfide-containing wastewater.
Participantes
| Rol | Sustancia | Coeficiente | Estado |
|---|---|---|---|
| Reactivo | Hydrogen Sulfide H₂S | 1 | (g) |
| Reactivo | Chlorine Cl | 1 | (g) |
| Producto | Sulfur S | 1 | (s) |
| Producto | Hydrochloric Acid HCl | 2 | (g) |
Ejemplo cotidiano
The rotten egg smell of hydrogen sulfide from sewers can be eliminated by chlorination, which oxidizes H₂S to odorless elemental sulfur.
Importancia industrial
La eliminación del H₂S mediante oxidación con cloro se usa en el endulzamiento del gas natural, el tratamiento de aguas residuales y en el refino del petróleo para prevenir la corrosión.
Propiedades
- Tipo
- Redox
- Reversible
- No
- Energía
- Exotérmico
- ΔH
- -186,0 kJ/mol