Iron(II) to Iron(III) Oxidation by Oxygen
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4Fe2+ + O2 + 4H+ → 4Fe3+ + 2H2O
Descripción general
Ferrous ions (Fe²⁺) are oxidized to ferric ions (Fe³⁺) by dissolved oxygen in acidic solution. This reaction is responsible for the yellowing of iron-containing groundwater upon exposure to air. The green Fe²⁺ solution turns yellow-brown as Fe³⁺ forms.
Participantes
Ejemplo cotidiano
Well water that is clear underground but turns rusty brown when left standing is undergoing this oxidation of dissolved iron(II) by air.
Importancia industrial
La química redox del hierro(II)/hierro(III) es fundamental para el tratamiento del agua, la geoquímica, la ciencia del suelo y la ingeniería de la corrosión en múltiples industrias.
Propiedades
- Tipo
- Redox
- Reversible
- No
- Energía
- Exotérmico
- ΔH
- -176,0 kJ/mol