Calcium Oxalate Precipitation (Kidney Stones)
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CaCl2 + Na2C2O4 → CaC2O4↓ + 2NaCl
Descripción general
Calcium chloride reacts with sodium oxalate to form a white precipitate of calcium oxalate (Ksp = 2.3 × 10⁻⁹). Calcium oxalate is the primary component of approximately 80% of kidney stones. The monohydrate form (whewellite) is thermodynamically favored and forms the hardest, most painful stones.
Participantes
| Rol | Sustancia | Coeficiente | Estado |
|---|---|---|---|
| Reactivo | Oxalic Acid C₂H₂O₄ | 1 | (aq) |
| Producto | Sodium Chloride NaCl | 2 | (aq) |
Ejemplo cotidiano
Most kidney stones are calcium oxalate crystals. Foods high in oxalate (spinach, rhubarb, almonds) can increase stone risk.
Importancia industrial
Comprender la precipitación del oxalato de calcio es crítico en nefrología, ciencia de los alimentos (análisis del contenido de oxalato) y en la elaboración de cerveza (prevención de la piedra de cerveza).
Propiedades
- Tipo
- Precipitation
- Reversible
- No
- Energía
- Exotérmico
- ΔH
- -12,0 kJ/mol