Chromium(III) Hydroxide Precipitation
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CrCl3 + 3NaOH → Cr(OH)3↓ + 3NaCl
Descripción general
Chromium(III) chloride reacts with sodium hydroxide to form a green gelatinous precipitate of chromium(III) hydroxide (Ksp = 6.3 × 10⁻³¹). Cr(OH)₃ is amphoteric, dissolving in both excess acid and excess NaOH. In excess NaOH, it forms the green chromite ion [Cr(OH)₄]⁻.
Participantes
| Rol | Sustancia | Coeficiente | Estado |
|---|---|---|---|
| Reactivo | Sodium Hydroxide NaOH | 3 | (aq) |
| Producto | Sodium Chloride NaCl | 3 | (aq) |
Ejemplo cotidiano
The green color of some gemstones like emerald is due to chromium(III) ions, the same oxidation state that produces this green precipitate.
Importancia industrial
La precipitación del hidróxido de cromo(III) se utiliza en la eliminación de cromo de aguas residuales industriales, particularmente de efluentes de cromado y curtido de cuero.
Propiedades
- Tipo
- Precipitation
- Reversible
- No
- Energía
- Exotérmico
- ΔH
- -90,0 kJ/mol