Synthesis of Acetic Acid (Monsanto Process)
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CH3OH + CO → CH3COOH
Descripción general
Methanol reacts with carbon monoxide in the presence of a rhodium-iodide catalyst to form acetic acid. The Monsanto process (and its successor, the Cativa process using iridium) is the dominant industrial method for acetic acid production.
Participantes
| Rol | Sustancia | Coeficiente | Estado |
|---|---|---|---|
| Reactivo | Methanol CH₃OH | 1 | (l) |
| Reactivo | Carbon Monoxide CO | 1 | (g) |
| Producto | Acetic Acid CH₃COOH | 1 | (l) |
Ejemplo cotidiano
White vinegar contains approximately 5% acetic acid, though commercial vinegar is typically produced by fermentation rather than this industrial process.
Importancia industrial
Principal ruta industrial para la producción de ácido acético, materia prima de acetato de vinilo, PET y disolventes.
Propiedades
- Tipo
- Synthesis
- Reversible
- No
- Energía
- Exotérmico
- ΔH
- -138,6 kJ/mol
- Catalizador
- Rhodium/iodide complex